Thursday, May 21, 2020

The War Of 1812 Essay - 1130 Words

The adjournment of the war of 1812 led to three political process which changed the face of America forever. The market revolution, the westward expansion, and the rise of a vigorous political democracy established American policies which are still upheld today. These policies include reformed freedom, improved economic procedures and established a political democracy. Many changes evolved after the war of 1812, the first being the eradication of a one-party government. The election of 1816 is significant for a few reasons. First, this election marks the end of federalist candidates. Rufus King was the last federalist candidate to run for presidency. However, King was out beat in â€Å"a vote of 65 to 54† by his democratic- republican competitor James Monroe (Preston). After Monroe’s victory, he worked to rid the federalist party, separate political parties and unify the nation. Following the war of 1812 and into Monroe’s presidency, the nation still felt grea t tension and separation. In hopes to rectify the situation, Monroe went on a tour to instill unity and nationalism. Trying to appeal to the common people Monroe payed his own way and dressed alike (Enclyopedia.com). His good will tour to boston coined the term â€Å"Era of Good Feeling† by an American journalist, Benjamin Russell (Boundless). Afters Monroe s two term presidency came the election of 1824. This election was met with great controversy. There were four candidates John Quincy, Henry Clay, and Andrew Jackson.Show MoreRelatedThe War of 1812672 Words   |  3 PagesThe War of 1812 was caused by the many conflicts with Great Britain and France. Even though the United States had made many efforts to stay out of the Napoleonic Wars, the conflict was not avoided. The United States had three primary reasons for declaring war: impressments and violations of trading rights, Indian conflicts, and a desire for western territory. For many years Great Britain and France violated the United States’ neutral shipping rights by confiscating American ships and impressingRead MoreWar of 18121643 Words   |  7 PagesThe War of 1812 was a war between Britain and the United States fought primarily in Upper Canada. It had many causes, few which involved British North America. The results of the war include the fact that there was no clear winner or loser among them. The only real losers in the situation were the Natives in the region. They were driven out of their lands and customs. None of the borders was changed by the war, though many attempts were made. The Treaty of Ghent, which ended the war, did nothingRead MoreWar Of 1812 : War1197 Words   |  5 PagesWar of 1812 Essay The War of 1812 was battled between the Assembled States and Britain. Finishing in 1815 with the Settlement of Ghent, the war did not achieve any of the issues it was being battled about. For the US, the War of 1812 appeared to simply be one disappointment after another. Despite the fact that the military endured awesome disappointment amid the war, these were the immediate result of the disappointment of the nationals to join for the reasons for the war. In light of these disappointmentsRead MoreThe War of 18121132 Words   |  4 PagesWar of 1812 The War of 1812 was started by America due to British encroachment on three fronts, trade restrictions imposed by the British, the increasing alliances of the British with Indian tribes blocking American expansion West, and due to British interference with merchant class ships in the Atlantic. The war was fought in the Great Lakes region between America and Canada, near New Orleans in the Gulf of Mexico, in the Atlantic trade routes, and around Washington DC. The British had alwaysRead MoreThe War Of 1812867 Words   |  4 PagesThe build up to the War of 1812 began nearly a decade prior to the start of the military action. Jefferson and the Republican vision slashed spending and government all around, leaving the military depleted and operating on Jefferson s â€Å"Gun Boat Diplomacy,† which meant America had just enough boats to protect American coasts but not enough to partake in any offshore activities. This left America vulnerable to the tactics employed by the British w hen combat resumed between England and France, andRead MoreThe War Of 18123664 Words   |  15 Pagestheir grievances from the War of 1812. They were concerned by growing power of federal government, even though they wanted to start new from England, the majority wanted a moderate compromise. Discussed 3/5 compromise, Louisiana Purchase, Embargo of 1807. 2.Impressment Main cause of the war of 1812, where British ships took over american merchant ships and kidnapped merchants to join the British navy. America used this as the main reason to declare war for the War of 1812 because of nationalism andRead MoreWar : The War Of 18121543 Words   |  7 PagesIntro From being a well-known war hero in the War of 1812 to becoming the 7th president of the United States, Andrew Jackson lived a marvelous life. His past life may have affected him greatly, but it never stopped him from moving to one role to another. Furthermore, not only was he president, but he was also a major general in the army and has been very victorious and successful in leading his troops. Jackson had gone through great lengths to obtain his position and popularity as president. He wasRead More War of 1812 Essay1612 Words   |  7 Pagesnbsp;nbsp;nbsp;nbsp;nbsp;The War of 1812 was a war between Britain and the United States fought primarily in Upper Canada. It had many causes, few whic h involved British North America. The results of the war include the fact that there was no clear winner or loser among them. The only real losers in the situation were the Natives in the region. They were driven out of their lands and customs. None of the borders was changed by the war, though many attempts were made. The Treaty of Ghent, which ended the war, did nothingRead More The War of 1812 Essay1090 Words   |  5 Pages The War of 1812 was fought between the United States and England. Ending in 1815 with the Treaty of Ghent, the war did not accomplish any of the issues it was being fought over. For the US, the War of 1812 seemed to just be one failure after another. Although the military suffered great failure during the war, these were the direct consequence of the failure of the citizens to unite for the causes of the war. Because of these failures, it is quite valid to call the War of 1812 quot;Americas worst-foughtRead More The War of 1812 Essay1307 Words   |  6 Pag esThe War Of 1812 The War of 1812 took place while president James Madison was in office. Madison was born in Orange County, Virginia in 1751. He attended the College of New Jersey, which is now well known as Princeton. Madison did many significant things both before and after he was in office. He participated in the framing of the Virginia Constitution, served in the Continental Congress and he was also a leader in the Virginia Assembly. One of his major contributions was a ratification to the Constitution

Wednesday, May 6, 2020

Synthesis and Ir Analysis of...

Synthesis and IR Analysis of trans-[Bis(inosinato)palladium(II)] Abstract In this lab we synthesized trans-[Bis(inosinato) palladium(II)] for IR analysis. After completion of the reaction 84.4% of the product was collected. IR spectrum of the product and inosine was analyzed to determine how the inosine is bonded to the metal, palladium. From the IR analysis, it was determined that when inosine reacts with palladium, a shift of about 65 cm-1 in the carbonyl stretch was observed. Introduction: In this experiment, trans-[Bis(inosinato)palladium(II)], was synthesized. The general reaction equation for the reaction is shown below: KOH (1) K2[PdCl4] + 2 inosine trans-[Pd(inosine-H+)2] +†¦show more content†¦A total of 1.5 mL was added to produce a pH of around 6. The mixture was stirred for an additional 30 minutes. The light yellow precipitate was collected by suction filtration using a Hirsch funnel. The product was washed with two 1-mL portions of cold methanol followed by two 1-mL portions of diethyl ether. The product was dried in the oven at 110 °C. The IR spectrum as a KBr pellet was obtained for the product and inosine for analysis. Results and Discussion: After completion of the reaction, the percent yield was collected for the product and is shown in Table 1. Synthesis of the yellow solid Trans-[Bis(inosinato)palladium(II)] was 84.4%. Table 1. Synthesis Results | Compound | Yield | Appearance | 1 | Trans-[Bis(inosinato)palladium(II)] | 84.4 % | Yellow solid | The result from the IR spectra for Trans-[Bis(inosinato)palladium(II)], and inosine are summarized in Table 2 and 3. It is important to note that Trans-[Bis(inosinato)palladium(II)] compound had an extra carbonyl peak at 1712.21 cm-1 which is from inosine impurity. Table 1. IR ANALYSIS: trans-[Bis(inosinato)palladium(II)] Frequency (cm−1) | Bond Responsible | 3388.55 | O-H stretch | 2928.24 | SP ³ C-H stretches | 1712.21 | C=O inosine impurity | 1636.64 | C=O with Pd-O interaction | 1327.48 | C-N stretch aromatic | 1080.15 | C-O ether stretch | Table 2. IR

The Perfect Storm and the Titanic analysis Free Essays

The Perfect Storm and the Titanic are both films that are based on true events; they also contain fictional plots and characters. This combination of fact and fiction is the main reason for these accounts becoming films rather than documentaries or other information based programme, as it includes an extra area of interest into the film which would usually be flat because of the droning historical backgrounds. To increase the tension and sympathy felt by the audience at each climatic ending, the directors both use the fictional plots. We will write a custom essay sample on The Perfect Storm and the Titanic analysis or any similar topic only for you Order Now They take this fact and fiction as a n advantage, and because of this both plots are based on romance, and the people involved around the love. In the case of Jack and Rose, their love creates more tension and sympathy at the ending because it is a forbidden love across the class boundaries of rich and poor, but which seems to be so strong. Bobby and Kristina’s love is open and strong. By using these romantic liaisons and including many biographical details throughout the films, it increases the depth of the emotions felt by the audience. This is clearly seen in the Perfect Storm when as the ship is beginning to sink and the camera is showing clips of the crew below deck, Murphy says to the person he is with, ‘this is gonna be hard on my son. ‘ This has a direct impact on the audience as earlier in the film he tried to explain to his son that: his mother might remarry or get a new partner; then he would be his father as well; the young boy does not like this idea and wants his father to stay. Because of this knowledge from earlier in the film it also makes the audience sad for the families of the dead because in the end the only reason they were going was because they wanted to bring in money for their families, but the skipper only wanted to go to bring up his weights in the fish market. Due to both these films developing from actual events, it is crucial for both of these films settings to be fully detailed to add emphasis to the authenticity and credibility of the films. Titanic was an extremely expensive film because of the directors adhering themselves completely to the effect authenticity could have on a film and the way it would make the fictional plot more plausible. The characters were attired in costumes of the period, also the quality of the clothes the actors wore was different to help enforce the class boundaries and the forbidden love between Jack and Rose; in the Perfect Storm the ship is strewn with copious amounts of paraphernalia required for deep sea fishing. The rugged disorganisation emits to the audience an atmosphere of frequent use which takes its toll on the boat and the crew who seem to be continuously draw to the punishment of the sea. To add emphasis to the setting and feeling of hopelessness when the Titanic begins to sink, a short clip is included. It only lasts for a couple of seconds but that is enough for it to have an impact on the audience. It shows the Titanic in all its glowing glory, in the middle of the pitch black Atlantic Ocean, the water is so dark you can’t tell where the water is and where the sky is. The music in both films seems to be centred on an orchestra. During scenes when there is great suspense, tension and danger the music changes. It becomes thicker and louder, the tempo often increases and there is a contrast between the length and the pitch of notes and the instruments used. There are long, quite high pitched notes being played by wind and string instruments, with the quickening drum beats and low wind instrument blasts, which are often accompanied by clashing cymbals. This type of music occurs in both films: in the Titanic when the ship hits the iceberg; during the Perfect Storm when the helicopter crashes and while the crew attempt an about turn with the boat. During ‘tender’ moment, the sound changes dramatically. For instance, when Rose and Jack are reunited, the music fades into the compassionate theme tune, which is played stridently over the top of resonating sound of the two lovers running feet. The effect of this is to emphasise the audience’s awareness of the absolute love felt between them. This use of love in each film brings conflicting thoughts into the heads of the audience. For some reason, the audience feels compassionate towards the plight of the characters, almost admiring them for their bravery in the face of danger, but in both films it was clearly the decision of the individuals themselves to undertake the journeys. In the Perfect Storm this idea is again conflicted with the audience’s knowledge that most of the people are only going on the voyage to raise funds so they can support their families. In the end the feeling of the audience towards the characters within the film is one of sympathy because the characters are trying to be the people they are expected to be; to live up to standards and to push the boundaries of anticipation; to provide more for their families so that they can live a better life almost to the point of foolhardiness. During the Perfect Storm when the boat reaches the eye of the storm, there are many alterations in the film to effect the mood and feelings of the audience. The music undergoes an almost undetectable metamorphosis, slipping gently between the dramatically thick, heavy use of instruments in the time of danger, slowly filtering out most of the noise to leave a lightly textured tone of long high wind and string notes. In the duration of this scene the lighting is also subtly changed. The first shot is from outside the boat, surrounded by tumbling waves and rolling dark clouds. The camera is then focused on the bridge of the Andrea Gale in an interior shot and onto the faces of William and Bobby. The bridge is surrounded by an almost glaring darkness. As they hit the eye of the storm, their faces are slowly illuminated by a rich honey coloured light. The camera changes to a shot from within the bridge of the boat. The audience’s eye is lead, out over the prow of the boat onto a large zone of calm, soothingly lapping water bathed in the rich ambiance of the light from between the parted huge billowing cumulus clouds. The expressions on the faces of the crewmen change to facades of wonder. But these expressions are quickly transformed to their former selves as the subtle light fades into the darkness. At this point the audience’s senses are heightened to the emotions of the characters and the audience feels a sudden heaviness which makes them sympathetic as they can see the process of realization that occurs on the crew as the find they are at the centre of the storm. This use of lighting is also used on the Titanic. The lights on the ship begin to flicker on and off soon after the collision with the iceberg. This is a successful technique as it mingles with the audience’s knowledge that they already have of the historical background to the film. This makes the audience nervous as they can see the upper class going around like it was any other day on the ship, as they believe the ship to be unsinkable and do not realise the immediate danger to their lives. To add to the extent of the effect that the lighting has on the audience, many techniques are used at the same time in conjunction with one another. This is often the case with lighting and camera angles. For instance, in both films to emphasise the tremendous tragedies of each accident, series of short clips are added in the endings. In the Perfect Storm the camera quickly concludes the lives of each character below deck by focusing on them during their last moments, this takes you around the below deck area of the ship as each man seems to be in the place most familiar to them. This cutting to and from each character adds to the authenticity of each character’s life as their emotions are plainly seen and have a large impact on the audience. This is also used in the Titanic, as the quartet plays out it’s final ballad flashing images are shown that correspond to earlier in the film when you see the lower classes being locked below deck. The images include: two elderly people lying together on their bed saying their last goodbyes, the camera is above them to show the water rising around them; an Irish woman telling her children a bedtime story to make them sleep and try to reduce their suffering. This is almost from the perspective of the children to show how this grieves the mother: the faces of the ship stewards as they continue to try and keep the lower classes down below where they will inevitably die; Dr. Andrews standing alone on the lounge of the upper class contemplating the fate of many that he knew should this situation occur would die, the shot is sweeping and on an angle, drawing through the lounge to the dining room where the floor is completely submerged in water on which most of the furniture is floating. Throughout these clips the lighting flashes constantly or is completely cut off, surrounding the people in the darkness of their imminent expiration. How to cite The Perfect Storm and the Titanic analysis, Papers